Opuntia ficus-indica (OFI) mucilage as corrosion inhibitor of steel in CO2-contaminated mortar

abstract

© 2021 by the authors. Licensee MDPI, Basel, Switzerland.The present investigation is directed to determine if a natural/botanical addition, from Op-untia ficus-indica (OFI) cactus, increases durability for cement-based materials exposed to CO2-laden environments (urban and industrial). The use of this botanical addition in cement-based material applications has shown good performance when these materials are exposed to chloride-laden environments, but no investigations to date have shown the performance of this addition in ur-ban/industrial environments. Therefore, the aim of this investigation is to complement OFI mucilage performance in the most hazardous environments where most of these construction materials are naturally exposed: marine, urban, and industrial. Steel-reinforced mortar prisms, containing OFI mucilage at different addition levels (0%, 1.5%, 4%, 8%, 42%, and 95%, by water mass replacement concentration), were exposed for 14 years (5110 days) in a natural CO2-laden environment. Linear polarization resistance measurements were performed in a wet¿dry cycle (between 5020 and 5110 days of age, after mortar fabrication) to determine the possible corrosion-inhibiting effect of OFI mucilage additions. Little corrosion-induced cracking was observed in carbonated mortars with OFI mucilage additions, compared with the carbonated control mortar that showed high corrosion-induced cracking. The electrochemical results showed corrosion-inhibiting efficiencies for steel in carbonated mortar with OFI mucilage additions of 40¿70% for low OFI mucilage concentrations (1.5% and 4%), and 70¿90% for medium and high OFI mucilage concentrations (8%, 42%, and 95%). Experimental findings suggest that adding OFI mucilage might be useful as a corrosion inhibitor for steel in carbonated cement-based materials (i.e., mortar) because corrosion rates and cracking initiation/propagation were decreased.