Effects of External Resistance, New Electrode Material, and Catholyte Type on the Energy Generation and Performance of Dual-Chamber Microbial Fuel Cells

In this study, the effects of an external resistance, new electrode material, and non-conventional catholyte on the energy generation and performance of a dual-chamber MFC were evaluated. Ten different resistances (15 ¿¿220 k¿), hydrophilically-treated graphene and graphite electrodes, and a 0.1 M HCl solution as a catholyte were assessed. The results showed that greater energy generation and power density were achieved at an external resistance of 2 k¿ and internal resistance between 2 and 5 k¿ on average; meanwhile, the greatest coulombic efficiency was obtained at the lowest external resistance evaluated (15 ¿). Therefore, it is recommended to operate the MFCs at the external resistance between 2 and 5 k¿ to ensure the maximum power generation of the dual chamber MFCs. Regarding the two electrode materials evaluated as an anode and cathode, hydrophilically-treated graphene was found to be a much better material to enhance the energy production and performance of the MFC system; therefore, its use is suggested in experimental and practical applications. On the other hand, the use of HCl as a catholyte enhanced the performance of MFC (constant and steady potential and greater coulombic efficiency) in most cases. © 2023 by the authors.